Claydol Big and Tall

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Debuts

 * Claydol

Major events

 * Ash's Baltoy evolves into Claydol and learns Ice Beam and Hyper Beam

Humans

 * Ash
 * May
 * Max
 * Brock
 * Jessie
 * James
 * Sigourney
 * Maiden (flashback)
 * Villagers

Pokémon

 * Pikachu (Ash's)
 * Meowth (Team Rocket's)
 * Wobbuffet (Jessie's)
 * Chimecho (James's)
 * Salamence (Ash's)
 * Swellow (Ash's)
 * Baltoy (Ash's; Evolves)
 * Claydol (Ash's; Newly Evolved; debut)
 * Lombre (Brock's)
 * Mudkip (Brock's)
 * Claydol (giant; debut)